83805-29-2Relevant academic research and scientific papers
Reaction Behaviour of Amides with Carbondisulphide and Isothiocyanates
Richter, M.,Strauss, K.,Schaedler, H.-D.,Augustin, M.
, p. 625 - 630 (2007/10/02)
Reactions of substituted arylamides, hetarylamides and furylacrylicamide 1 with carbon disulphide present a possibility to synthesize imino-dithiocarbonic-S,S'-diester 5.The mechanism of the reaction and the reaction conditions are investigated.Quantum chemical investigations by simple HMO-method in connection with the experimental results describe the reaction in dependence upon the influence of substituent in 2- and 4-position to the phenylring.Further more is describe the reaction of amide with isothiocyanates to thiourea 6 and isothiourea 7. The structures of the final products are determined by analytical dates.
