83805-62-3

Upstream product

• 20052-28-2 7-(Benzyloxy)-5-hydroxy-2-methyl-4H-1-benzopyran-4-one 
• 77-78-1 dimethyl sulfate 
• 1162-81-8 3-Acetyl-5,7-bis(acetyloxy)-2-methyl-4H-1-benzopyran-4-one 
• 1022-78-2 3-acetyl-5,7-dihydroxy-2-methyl-chromen-4-one 
• 1013-69-0 eugenin 
• 39548-89-5 1-(4-(benzyloxy)-2-hydroxy-6-methoxyphenyl)ethan-1-one 
• 83805-61-2 1-(4-benzyloxy-2-hydroxy-6-methoxyphenyl)-1,3-butanedione 

Downstream Products

• 83805-64-5 7-hydroxy-8-iodo-5-methoxy-2-methyl-4H-1-benzopyran-4-one 
• 35930-31-5 Alloptaeroxylin methyl ether 
• 29507-75-3 spatheliachromen 

Relevant academic research and scientific papers

A Convenient Synthesis of Linear 2-Methylpyranochromones

A convenient synthesis of linear 2-methylpyranochromones, viz., spatheliachromen(5-hydroxy-2,2,8-trimethyl-2H,6H-benzodipyran-6-one), O-methylspatheliachromen (5-methoxy-2,2,8-trimethyl-2H,6H-benzodipyran-6-one) (8) and O-methylallopteroxylin (5-methoxy-2,8,8-trimethyl-4H,8H-benzodipyran-4-one> is described by blocking the eighth position of the corresponding 7-propargyl ether derivative 7-(1,1-dimethyl-2-propynyloxy)-8-iodo-5-methoxy-2-methyl-4H-1-benzopyran-4-one with iodine followed by thermal cyclization.The linear pyranochromones 2,2,8-trimethyl-2H,6H-benzodipyran-6-one and 8 are also synthesized starting with the easily available appropriate 3,4-dihydro-2,2-dimethyl-2H-1-benzopyran-7-ols following the steps of Claisen condensation with ethyl acetate, cyclization with ethanolic sulfuric acid followed by dehydrogenation with NBS.