83846-22-4

Basic information

• Product Name: 1-Phenyl-9-methylbicyclo<3.3.1>nonan-9-ol
• CAS NO: 83846-22-4
• Molecular Weight: 230.35
• Mol File: 83846-22-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-Phenyl-9-methylbicyclo<3.3.1>nonan-9-ol(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Phenyl-9-methylbicyclo<3.3.1>nonan-9-ol(83846-22-4)
• EPA Substance Registry System: 1-Phenyl-9-methylbicyclo<3.3.1>nonan-9-ol(83846-22-4)

Safety Data

• Hazardous Substances Data: 83846-22-4(Hazardous Substances Data)

Upstream product

• 36399-42-5 1-Phenyl-bicyclo<3.3.1>nonan-9-on 
• 74-88-4 methyl iodide 

Downstream Products

• 83846-23-5 cis-3a-Methyl-4-phenyl-2,3,3a,6,7,7a-hexahydroindene 
• 51953-76-5 1-Phenyl-9-methylenebicyclo<3.3.1>nonane 

Relevant articles and documents

Dehydration of 1-Substituted Secondary and Tertiary Bicyclononan-9-ols. A Substituent-Driven Rearrangement to 4-Substituted and/or Angularly Substituted Hexahydroindenes

The acid-catalyzed dehydration of substituted bicyclononan-9-ols (1-9) has been studied as a route to substituted hexahydroindenes via skeletal rearrangement.The nature of the substituent at C1 strongly affects the rearrangement.Thus 1-substituted secondary alcohols 1-3 (R = Ph, CH3, H) afford 4-substituted 2,3,4,5,6,7-hexahydroindenes 1b-3b, while a mixture of 3a-carbethoxyhexahydroindenes (4a,b) is produced from 4 (R = CO2Et).Tertiary alcohols 5-9 afford cis-3a-substituted 2,3,3a,6,7,7a-hexahydroindenes 1a-9a.These processes are discussed in terms of relative stabilities of the intermediate carbonium ions.