83855-86-1

Basic information

• Product Name: N,N-dimethyldodecan-1-amine
• Synonyms: N,N-dimethyldodecan-1-amine
• CAS NO: 83855-86-1
• Molecular Formula: C14H31N
• Molecular Weight: 0
• Mol File: 83855-86-1.mol
• Article Data: 54

Chemical Properties

• Appearance: /
• CAS DataBase Reference: N,N-dimethyldodecan-1-amine(CAS DataBase Reference)
• NIST Chemistry Reference: N,N-dimethyldodecan-1-amine(83855-86-1)
• EPA Substance Registry System: N,N-dimethyldodecan-1-amine(83855-86-1)

Safety Data

• Hazardous Substances Data: 83855-86-1(Hazardous Substances Data)

Upstream product

• 112-53-8 1-dodecyl alcohol 
• 124-40-3 dimethyl amine 
• 4292-19-7 1-Iodododecane 
• 112-52-7 1-chlorododecane 
• 75-50-3 trimethylamine 
• 67-56-1 methanol 
• 124-22-1 n-Dodecylamine 
• 3007-53-2 N,N-dimethyldodecanamide 
• 143-07-7 lauric acid 
• 111-82-0 methyl n-dodecanoate 
• 64-18-6 formic acid 
• 1643-20-5 dodecyl-N,N-dimethylamine N-oxide 
• 29493-00-3 dodec-6-ene 
• 201230-82-2 carbon monoxide 

Downstream Products

• 29811-96-9 [2-(2-chloro-phenoxy)-ethyl]-dodecyl-dimethyl-ammonium; bromide 
• 4728-59-0 dodecyl-(2-hydroxy-3-phenoxy-propyl)-dimethyl-ammonium; chloride 
• 71242-01-8 [(benzyl-methyl-carbamoyl)-methyl]-dodecyl-dimethyl-ammonium; chloride 
• 39923-13-2 dodecyl-dimethyl-(4-nitro-benzyl)-ammonium; chloride 
• 120639-15-8 [(4-chloro-phenylcarbamoyl)-methyl]-dodecyl-dimethyl-ammonium; chloride 
• 10561-60-1 dodecyl-dimethyl-(2-phenoxy-ethyl)-ammonium; chloride 

Relevant articles and documents

Method for realizing N-alkylation by using alcohols as carbon source under photocatalysis

The invention discloses a method for realizing N-alkylation by using alcohols as a carbon source under photocatalysis, and belongs to the technical field of catalytic synthesis. Alcohol, a substrate raw material and a catalyst are placed in a reaction device, ultraviolet and/or visible light irradiation is carried out in an inert atmosphere, after the irradiation is finished, solid-liquid separation is carried out to remove the catalyst, and an N-alkylation product can be obtained through extraction, distillation and purification, wherein the substrate raw material comprises any one of an amine compound, an aromatic nitro compound or an aromatic nitrile compound, the alcohol comprises any one or more of soluble primary alcohols, and the catalyst is metal oxide/titanium dioxide or metal sulfide/titanium dioxide. The method is simple and easy to operate, can be used for efficient photocatalysis one-pot multi-step hydrogenation N-alkylation reaction, and is mild in reaction condition, high in chemical selectivity of N-alkylamine, good in catalyst stability and easy to recycle.

SUPPORTED HETEROGENEOUS CATALYST, PREPARATION AND USE THEREOF

A supported heterogeneous catalyst comprises rhodium and vanadium on a support, wherein the supported heterogeneous catalyst is preparable by depositing vanadium on a supported rhodium catalyst by impregnation. A process for preparing the aforementioned catalyst and a process for converting an amide into an amine in the presence of the aforementioned catalyst are provided.

N-Methylation of amines and nitroarenes with methanol using heterogeneous platinum catalysts

We report herein the selective N-methylation of amines and nitroarenes with methanol under basic conditions using carbon-supported Pt nanoparticles (Pt/C) as a heterogeneous catalyst. This method is widely applicable to four types of N-methylation reactions: (1) N,N-dimethylation of aliphatic amines under N2, (2) N-monomethylation of aliphatic amines under 40 bar H2, (3) N-monomethylation of aromatic amines under N2, and (4) tandem synthesis of N-methyl anilines from nitroarenes and methanol under 2 bar H2. All these reactions under the same catalytic system showed high yields of the corresponding methylamines for a wide range of substrates, high turnover number (TON), and good catalyst reusability. Mechanistic studies suggested that the reaction proceeded via a borrowing hydrogen methodology. Kinetic results combined with density functional theory (DFT) calculations revealed that the high performance of Pt/C was ascribed to the moderate metal–hydrogen bond strength of Pt.