83864-73-7

Basic information

• Product Name: 3β-[[2-O-(6-Deoxy-α-L-mannopyranosyl)-α-L-arabinopyranosyl]oxy]-24-hydroxy-5α-olean-12-en-28-oic acid
• Synonyms: 3β-[[2-O-(6-Deoxy-α-L-mannopyranosyl)-α-L-arabinopyranosyl]oxy]-24-hydroxy-5α-olean-12-en-28-oic acid;Prosapogenin CP3a
• CAS NO: 83864-73-7
• Molecular Formula: C₄₁H₆₆O₁₂
• Molecular Weight: 750.95554
• Mol File: 83864-73-7.mol
• Article Data: 6

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 3β-[[2-O-(6-Deoxy-α-L-mannopyranosyl)-α-L-arabinopyranosyl]oxy]-24-hydroxy-5α-olean-12-en-28-oic acid(CAS DataBase Reference)
• NIST Chemistry Reference: 3β-[[2-O-(6-Deoxy-α-L-mannopyranosyl)-α-L-arabinopyranosyl]oxy]-24-hydroxy-5α-olean-12-en-28-oic acid(83864-73-7)
• EPA Substance Registry System: 3β-[[2-O-(6-Deoxy-α-L-mannopyranosyl)-α-L-arabinopyranosyl]oxy]-24-hydroxy-5α-olean-12-en-28-oic acid(83864-73-7)

Safety Data

• Hazardous Substances Data: 83864-73-7(Hazardous Substances Data)

Upstream product

• 76729-67-4 hederagenin 3-O-β-D-glucopyranosyl-(1->4)-β-D-glucopyranosyl-(1->4)-β-D-ribopyranosyl-(1->3)-α-L-rhamnopyranosyl-(1->2)-α-L-arabinopyranoside 
• 60213-75-4 C₅₃H₇₈O₁₈ 
• 29781-27-9 C₅₂H₈₄O₂₁ 
• 33289-85-9 Dipsacosid B 
• 29321-28-6 hederogenin 3-O-β-D-xylopyranosyl-(1-3)-α-L-rhamnopyranosyl-(1-2)-α-L-arabinopyranoside 
• 76729-67-4 hederagenin 3-O-β-D-glucopyranosyl-(1-4)-β-D-glucopyranosyl-(1-4)-β-D-xylopyranosyl-(1-3)-α-L-rhamnopyranosyl-(1-2)-α-L-arabinopyranoside 
• 29781-27-9 hederagenin 3-O-β-D-glucopyranosyl-(1-4)-β-D-xylopyranosyl-(1-3)-α-L-rhamnopyranosyl-(1-2)-α-L-arabinopyranoside 
• 128717-92-0 3-O-α-L-rhamnopyranosyl(1->2)-α-L-arabinopyranosyl-hederagenin 28-O-β-D-xylopyranosyl(1->6)-β-D-glucopyranosyl ester 

Downstream Products

• 73-34-7 L-rhamnose 
• 87-72-9 L-(+)-arabinose 
• 465-99-6 hedaragenin 
• 83944-28-9 (3β,4a)-3,23-dihydroxyoleanolic-12-en-28-oic acid 
• 449173-64-2 methyl α,β-L-arabinopyranoside 
• 1128-40-1 methyl L-rhamnopyranoside 
• 465-99-6 3β,23-Dihydroxy-olean-12-en-28-oic acid 

Relevant articles and documents

Synthesis of α-hederin, δ-hederin, and related triterpenoid saponins

The synthesis of α-hederin (3-O-[α-L-rhamnopyranosyl-(1→2) -α-L-arabinopyranosyl]hederagenin, 1), δ-hederin (3-O-(α-L-arabinopyranosyl)hederagenin, 3), and three related triterpenoid saponins is described as part of a study of the structure-activity relationships between triterpenoid saponins and hemolytic activity. 4-Methoxybenzyl α-L-arabinopyranoside (11) was synthesized first and then used to prepare the different arabinose acceptors. Glycosylation between the acceptors and 2,3,4-tri-O-benzoyl-α-L-rhamnopyranosyl trichloroacetimidate (20) was performed in excellent yield to give the desired disaccharides. Coupling of the trichloroacetimidate derivatives of the disaccharides to allyl- or methyl-hederagenin gave the protected saponosides in high yields. The saponins and their corresponding methyl esters were then obtained in good to moderate yields after deprotection. Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004.

On the Structure of Saponins from Astrantia major L. Part 38: On the Knowledge of the Constituents of Some Saniculoideae

From fresh plant material of Astrantia major L. a complex of saponins was isolated and separated into its main components.The complex comtains mono- and bisdesmosides with triterpene acids as aglycon.The dominating part of glycosides at C-3 of the aglyca is the 3-O-α-L-rhamnopyranosyl-(1->2)-α-L-arabinopyranoside linked with hederagenin (α-hederin) or oleanolic acid (β-hederin) and bisdesmosidically as hederagenin-28-O-L-rhamnopyranosylester (hederasaponin C) and as hederagenin-28-O-D-glucopyranosyl-(1->6)-D-glucopyranosylester (diipsacosid B).Furthermore a gypsogenic acid-3-O-D-glucopyranosyl-(1->2)-glucopyranosid was identified.

Studies on the constituents of Clematis species. III. On the saponins of the root of Clematis chinensis Osbeck

-