83867-63-4Relevant academic research and scientific papers
INTRAMOLECULAR DIELS-ALDER REACTION WITH FURAN-DIENE. AN EXPEDITIOUS ENTRY INTO A FUNCTIONALIZED GIBBANE.
Grootaert, Werner M.,De Clercq, Pierre J.
, p. 3291 - 3294 (2007/10/02)
A short synthesis of a functionalized gibbane is described.The key-step involves the intramolecular Diels-Alder reaction of furan-diene 12, leading to a 1:3 ratio of two diastereoisomers, tentatively identified as 14a and 14b.The precursor 12 is obtained
