838825-87-9Relevant academic research and scientific papers
Anion recognition and redox sensing by a metalloporphyrin-ferrocene- alkylammonium conjugate
Bucher, Christophe,Devillers, Charles H.,Moutet, Jean-Claude,Royal, Guy,Saint-Aman, Eric
, p. 1584 - 1589 (2004)
The synthesis and characterization of a novel redox molecular receptor is reported. This chemosensor is structured on a ferrocene fragment whose cyclopentadienyl moieties have been connected to distinct and complementary zinc porphyrin and alkylammonium binding sites, enabling multipoint recognition and detection of anionic species. Cumulative effects of multiple anchoring points on this ammonium-ferrocene-metalloporphyrin chemosensor allowed the unprecedented ferrocene-based voltammetric sensing of halide anions.
Self-assembly of a ferrocene-substituted porphyrin capable of electrochemically sensing neutral molecules via a tail on-tail off process
Bucher, Christophe,Devillers, Charles H.,Moutet, Jean-Claude,Royal, Guy,Saint-Aman, Eric
, p. 888 - 889 (2003)
The supramolecular assembly of a ferrocene-porphyrin conjugate allowed ferrocene-based electrochemical sensing of the metalloporphyrin axial coordination via a tail on-tail off binding process.
