838867-89-3Relevant academic research and scientific papers
Generation and electrophilic substitution reactions of 3-lithio-2-methyleneaziridines
Montagne, Cyril,Prévost, Natacha,Shiers, Jason J.,Prié, Gildas,Rahman, Sabitur,Hayes, Jerome F.,Shipman, Michael
, p. 8447 - 8457 (2007/10/03)
2-Methyleneaziridinyl anions can be produced by selective deprotonation of the parent aziridine at C-3 using sec-BuLi/TMEDA. Subsequent reaction with a wide variety of electrophiles including MeI, ICH2CH2CH2CH2C
A Lewis acid catalyzed intramolecular [4+3] cycloaddition route to polycyclic systems that contain a seven-membered ring
Prie, Gildas,Prevost, Natacha,Twin, Heather,Fernandes, Stephanie A.,Hayes, Jerome F.,Shipman, Michael
, p. 6517 - 6519 (2007/10/03)
(Chemical equation presented). Two simple steps, including a new intramolecular [4+3] cycloaddition, are required for the preparation of polycycles that contain a seven-membered ring from 2-methyleneaziridines (see scheme). The diene component is introduc
