838879-43-9

Basic information

• Product Name: [trans-Pt(C₆F₅)2(PEtPh₂)2]
• CAS NO: 838879-43-9
• Molecular Weight: 957.69
• Mol File: 838879-43-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [trans-Pt(C₆F₅)2(PEtPh₂)2](CAS DataBase Reference)
• NIST Chemistry Reference: [trans-Pt(C₆F₅)2(PEtPh₂)2](838879-43-9)
• EPA Substance Registry System: [trans-Pt(C₆F₅)2(PEtPh₂)2](838879-43-9)

Safety Data

• Hazardous Substances Data: 838879-43-9(Hazardous Substances Data)

Upstream product

• 607-01-2 ethyl-diphenyl-phosphane 

Relevant articles and documents

Insertion reactions of SnCl2 into Pt-Cl bonds in pentahalophenylplatinate(II) complexes

Several pentahalophenylplatinate complexes with Pt-Sn metal-metal bond have been synthesized by facile insertion of SnCl2 into Pt-Cl bonds of the starting complexes. The complexes have been characterized spectroscopically and, in the case of (NBu4)2[trans-Pt(SnCl 3)2(C6F5)2] and (NBu 4)2[trans-Pt2(μ-Cl)2(SnCl 3)2(C6F5)2], the structures have been determined by X-ray diffraction. The reactivity of these derivatives towards neutral ligands has also been explored. Several pentahalophenylplatinate complexes with Pt-Sn metal-metal bonds have been synthesized by facile insertion of SnCl2 into Pt-Cl bonds of the starting platinum substrates. The complexes have been characterized spectroscopically and, in the case of (NBu4)2[trans- Pt(SnCl3)2(C6F5)2] and (NBu4)2[trans-Pt2(μ-Cl) 2(SnCl3)2(C6F5) 2], the structures have been analyzed by X-ray diffraction. The reactivity of these derivatives towards neutral ligands has been explored. The electronic spectra of some selected derivatives have also been examined.