839-34-9Relevant academic research and scientific papers
New preparation of 1,2,4,5-tetraoxanes
Terent'ev,Kutkin,Starikova,Antipin,Ogibin,Nikishin
, p. 2356 - 2366 (2007/10/03)
A convenient procedure was developed for the synthesis of 1,2,4,5-tetraoxanes based on the reaction of gem-bishydroper-oxycycloalkanes with ketals and acetals catalyzed by boron trifluoride etherate, which makes it possible to prepare the target products
Dispiro-1,2,4-trioxolanes by Ozonolysis of Cycloalkylidenecycloalkanes on Polyethylene
Griesbaum, Karl,Krieger-Beck, Petra,Beck, Johannes
, p. 391 - 396 (2007/10/02)
Ozonolyses of symmetrical (1b-d) and of unsymmetrical cycloalkylidenecycloalkanes (8a, b) afforded the dispiro-1,2,4-trioxolanes 4b-d and 9a, b, respectively.Their thermal decompositions gave mixtures of the cyclic ketones (3) and lactones (6).Photolysis afforded in addition to 3 and 6 the cyclic anhydrides 13, which are isomeric with the corresponding disoiro-1,2,4-trioxolanes.
