83914-10-7

Upstream product

• 5724-61-8 2-oxabicyclo[3.2.1]octan-3-one 
• 1004-20-2 1-oxabicyclo<3.2.1>octan-2-one 
• 29667-59-2 4-methyl-2-oxabicyclo<3.2.1>octan-3-one 
• 29667-61-6 2-(3-hydroxycyclopentyl)propan-1-ol 
• 88249-88-1 (R)-3-((S)-2-Hydroxy-1-methyl-ethyl)-cyclopentanone 
• 98-59-9 p-toluenesulfonyl chloride 
• 83914-09-4 Toluene-4-sulfonic acid (R)-2-((1S,3R)-3-hydroxy-cyclopentyl)-propyl ester 

Downstream Products

• 88249-89-2 Toluene-4-sulfonic acid (S)-(R)-2-(1,4-dioxa-spiro[4.4]non-7-yl)-propyl ester 
• 88249-90-5 (1R,3R)-3-(R)-1,4-Dioxa-spiro[4.4]non-7-yl-1-(4-methoxy-bicyclo[4.2.0]octa-1⁽⁶⁾,2,4-trien-7-yl)-butan-1-ol 

Relevant academic research and scientific papers

A new Synthetic Approach to Quassinoids via an Intramolecular Diels-Alder Reaction: A Stereoselective Construction of the Klaineanone Ring System

Thermolysis of the benzocyclobutene derivative (25) prepared from norcamphor (6) gave stereoselectively the tetracyclic compound (27), which was converted into the D-deoxyquassinoid derivative (2) possessing the same ABCD-ring fusion as that of klaineanon

AN INTRAMOLECULAR DIELS-ALDER APPROACH TO QUASSINOIDS - A STEREOSELECTIVE CONSTRUCTION OF A-AROMATIC KLAINEANONE

Thermolysis of a benzocyclobutene derivative (20) prepared from norcamphor produced stereoselecively a tetracyclic compound (2), which was converted to a lactone (21) having correct stereochemistry at C7, C8, C9, C11