83933-44-2

Basic information

• Product Name: Cyclopropane, 3-(difluoromethylene)-1,1-difluoro-2,2-bis(trifluoromethyl)-
• CAS NO: 83933-44-2
• Molecular Formula: C6F10
• Molecular Weight: 262.05
• Mol File: 83933-44-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Cyclopropane, 3-(difluoromethylene)-1,1-difluoro-2,2-bis(trifluoromethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclopropane, 3-(difluoromethylene)-1,1-difluoro-2,2-bis(trifluoromethyl)-(83933-44-2)
• EPA Substance Registry System: Cyclopropane, 3-(difluoromethylene)-1,1-difluoro-2,2-bis(trifluoromethyl)-(83933-44-2)

Safety Data

• Hazardous Substances Data: 83933-44-2(Hazardous Substances Data)

Upstream product

• 428-59-1 Hexafluoropropene oxide 
• 22692-36-0 perfluoro-(3-methylbuta-1,2-diene) 

Downstream Products

• 1584-03-8 perfluoro-2-methylpent-2-ene 

Relevant articles and documents

Polyhalogeno-allenes and -acetylenes. Part 14. The reactions of Perfluoro-1,2-dienes with Dichloro- and Difluoro-carbene, and a New Route to 1,1-Dichloroperfluoro-1,2-dienes

Perfluoro-1,2-dienes RF(CF3)C=C=CF2 (RF = CF3 or n-C3F7) react in the gas phase with difluoro- and dichlorocarbene to give methylenecyclopropanes RF(CF3)CCF2C=CX2 (RF = CF3, n-C3F7; X = F, Cl) in good yield by an addition-rearrangement sequence.Pyrolysis of 1-dichloromethylene-3,3-difluoro-2,2-bis(trifluoromethyl)cyclopropane results in extrusion of difluorocarbene and the formation of 1,1-dichloro-4,4,4-trifluoro-3-trifluoromethylbuta-1,2-diene in high yield.This new allene reacts readily with methanol and undergoes efficient Diels-Alder additions to the perfluoroalkyl-substituted double bond.