839676-24-3Relevant academic research and scientific papers
Conjugate additions of a simple monosilylcopper reagent with use of the CuI-DMS complex: Stereoselectivities and a dramatic impact by DMS
Dambacher, Jesse,Bergdahl, Mikael
, p. 580 - 589 (2005)
(Chemical Equation Presented) Conjugate additions utilizing the simple monosilylcuprate reagent Li[PhMe2SiCuI] to α,β-unsaturated carbonyl compounds are described. The presence of dimethyl sulfide (DMS), either as a component originating from t
Platinum-catalyzed generation of silylenes from hydrodisilanes and their addition to α,β-unsaturated ketones
Okamoto, Kazuhiro,Hayashi, Tamio
, p. 108 - 109 (2008/09/20)
The reaction of hydrodisilanes with α,β-unsaturated ketones in the presence of a platinum catalyst gave high yields of oxasilacyclopentenes, which are probably formed by the addition of silylenes to the enones. Treatment of the oxasilacyclopentenes with methyllimium followed by hydrolysis gave the corresponding β-silyl ketones. Copyright
