83970-97-2Relevant academic research and scientific papers
Co-ordination Chemistry of Higher Oxidation States. Part 3. Palladium(IV) Complexes with Neutral Unidentate Ligands
Gulliver, David J.,Levason, William
, p. 1895 - 1898 (2007/10/02)
Oxidation of with the corresponding halogen (X2) in carbon tetrachloride gave octahedral palladium(IV) anions n3, X=Cl; L=PEt2Ph, X=Br>.Attemps toprepare analogues with L=SbMe3, TeMe2, or dmso (dimethyl sulphoxide) failed.Neutral palladium (IV) complexes trans- (L=NMe3, Py, PPrn3, or AsMe2Ph, X= Cl; L=NMe3, X= Br) have been obtained from trans- and X2.The complexes were characterised by i.r. and electronic spectroscopy, and conductivity measurements, and their thermal decomposition examined by t.g.a.
