83996-25-2Relevant academic research and scientific papers
AUTORECYCLING OXIDATION OF AMINES TO CARBONYL COMPOUNDS CATALYZED BY 3,4-DISUBSTITUTED 4-DEAZATOXOFLAVIN DERIVATIVES
Nagamatsu, Tomohisa,Hashiguchi, Yuko,Sakuma, Yoshiharu,Yoneda, Fumio
, p. 1309 - 1312 (1982)
3,4-Disubstituted 4-deazatoxoflavin derivatives (II) were prepared by the condensation of 6-(1-methylhydrazino)uracils (I) with appropriate α-diketones.The compounds II oxidized long-chain alkylamines such as n-octylamine and n-dodecylamine besides benzylamine and cyclohexylamine to yield the corresponding carbonyl compounds via imines, catalytically with a markedly high turnover number.
Synthesis and Properties of 3,4-Disubstituted 1-Methylpyrimidopyridazine-5,7(1H,6H)-diones (3,4-Disubstituted 4-Deazatoxoflavins) and 3,4-Disubstituted 4-Deazatoxoflavin Bound to Polystyrene and Their Use in Autorecycling Oxidation of Amines
Sakuma, Yoshiharu,Nagamatsu, Tomohisa,Hashiguchi, Yuko,Yoneda, Fumio
, p. 851 - 859 (2007/10/02)
3,4-Disubstituted 1-methylpyrimidopyridazine-5,7(1H,6H)-diones (3,4-disubstituted 4-deazatoxoflavins) and their analogues (II) were synthesized by the condensation of 6-(1-methylhydrazino)uracil derivatives (I) and appropriate α-diketones.Reduction
