84018-76-8Relevant academic research and scientific papers
Hydroformylation of Vinyl Sulfones and Sulfoxides Catalyzed by a Zwitterionic Rhodium Complex. A Diastereoselective Process
Totland, Karen,Alper, Howard
, p. 3326 - 3329 (2007/10/02)
The hydroformylation of unsaturated sulfones and sulfoxides catalyzed by η6-C6H5B-Ph3Rh+ (1,5-COD) (1) was achieved in excellent yield and regiocontrol, with exclusive formation of branched-chain aldehydes.In the case of phenyl vinyl sulfoxide, evidence is presented for stereoselectivity in the reaction.
