84019-67-0

Basic information

• Product Name: 2-formyloxy-1,4-dimethoxybenzene
• Synonyms: 2-formyloxy-1,4-dimethoxybenzene
• CAS NO: 84019-67-0
• Molecular Weight: 182.176
• Mol File: 84019-67-0.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: 2-formyloxy-1,4-dimethoxybenzene(CAS DataBase Reference)
• NIST Chemistry Reference: 2-formyloxy-1,4-dimethoxybenzene(84019-67-0)
• EPA Substance Registry System: 2-formyloxy-1,4-dimethoxybenzene(84019-67-0)

Safety Data

• Hazardous Substances Data: 84019-67-0(Hazardous Substances Data)

Upstream product

• 93-02-7 2,5-dimethoxybenzaldehyde 

Downstream Products

• 132681-41-5 2-(1,1-dimethylpropynyl)-5-(2-methylbut-3-yn-2-yloxy)-benzoquinone 4-dimethyl acetal 
• 132681-18-6 4-(2-methylbut-3-yn-2-yl)-2,5-dimethoxyphenyl 2-methylbut-3-yn-2-yl ether 
• 111316-21-3 1,4-dimethoxy-2-methoxymethyleneoxy-3-pentadecylbenzene 
• 111316-22-4 2-hydroxy-1,4-dimethoxy-3-pentadecylbenzene 
• 87746-49-4 1-((3,6-dimethoxy-2-methoxymethyleneoxy)phenyl)-10-pentadecen-1-ol 
• 87746-50-7 1-((3,6-dimethoxy-2-methoxymethyleneoxy)phenyl)-10-pentadecene 
• 87746-51-8 dimethoxymaesanin 
• 87863-10-3 3,6-Dimethoxy-2-<(Z)-10-pentadecenyl>phenol 
• 87746-54-1 1-(2,5-dimethoxyphenyl)-10-pentadecene 
• 87746-55-2 1,4-dimethoxy-2-(methoxymethoxy)benzene 
• 82380-21-0 maesanin 
• 21551-66-6 2,5-dimethoxy-3-pentadecylcyclohexa-2,5-diene-1,4-dione 
• 21551-64-4 2-hydroxy-5-methoxy-3-pentadecyl-1,4-benzoquinone 
• 411232-96-7 acrylic acid 2-(1,1-dimethyl-allyloxy)-3,6-dimethoxy-phenyl ester 

Relevant articles and documents

Diene-Transmissive Diels-Alder Sequences with Benzynes

Diene-transmissive Diels-Alder (DTDA) sequences are extraordinarily powerful processes for the generation of fused bicyclic systems. Nonetheless, only stable dienophiles have previously been deployed. Herein we report DTDA sequences with a variety of substituted [3]dendralenes in the first study to deploy arynes as dienophiles. We demonstrate the one-flask generation of complex, aromatic-ring-containing, multicyclic systems of relevance to medicinal chemistry. These synthetic operations provide numerous successful examples of the otherwise challenging and rarely reported intermolecular Diels-Alder reaction of acyclic 1,3-butadienes with arynes, which is made possible due to the exalted reactivity of dendralenic dienes.

Solid-phase synthesis of quinol fatty alcohols, design of N/O-substituted quinol fatty alcohols and comparative activities on axonal growth

Following the promising activity of Q2FA15 on axonal growth, two new series of N/O-substituted QFAs were synthesized, based on a SN2-type reaction. O-alkylated QFA bearing 14 carbon atoms on the side chain (n = 14) shows a very potent activity on axonal growth though lowered when compared to Q2FA15. While O-alkylation allows good retention of the biological activity, N-alkylation abolishes it nonetheless. A solid-phase-supported synthesis of Q2FA15 allowing the conception of new hybrid compounds is also described.

The oxidation of methoxy aromatic aldehydes with the system O2/iPrCHO/metal catalyst

The oxidation of methoxy aromatic aldehydes by the system O2/iPrCHO/metal catalyst proceeds in high yields of formates, almost without the formation of important quantities of carboxylic acids.