84040-22-2Relevant academic research and scientific papers
ADDITION REACTIONS OF SOME SIMPLE THIOALDEHYDES.
Baldwin, Jack E.,Lopez, Gerald R. C.
, p. 1487 - 1498 (2007/10/02)
When generated at 100 deg C, aliphatic and aromatic thioaldehydes without electronic bias are shown to undergo addition reactions to both aliphatic and aromatic 1,3-dienes.The reaction is shown to have application in an intramolecular example.
The Generation and Trapping of Thiobenzaldehyde and Thioacetaldehyde
Baldwin, Jack E.,Lopez, R. C. Gerald
, p. 1029 - 1030 (2007/10/02)
Thiobenzaldehyde and thioacetaldehyde have been generated by thermolysis of alkyl thiosulfinates under preparatively useful conditions and trapped with aromatic and aliphatic 1,3-dienes, the adducts with anthracene being convenient and high yielding sources of such thioaldehydes; thiobenzaldehyde has been shown to undergo the 'ene' reaction.
