84044-54-2Relevant academic research and scientific papers
SYNTHESIS AND TRANSFORMATIONS OF OXAZIRIDINES. ADAMANTANE-2-SPIRO-3'-OXAZIRIDINE AND ITS N-ALKYL DERIVATIVES
Novoselov, E. F.,Isaev, S. D.,Yurchenko, A. G.
, p. 97 - 103 (2007/10/02)
Unsubstituted and N-substituted adamantane-2-spiro-3'-oxaziridine were synthesized by the oxidation of Schiff bases, obtained from adamantanone and alkyl(aryl)amines, with peroxyacetic acid.The thermal rearrangement of the N-substituted derivatives leads to N-substituted 5-azahomoadamantan-4-ones, while fragmentation under the influence of Fe(II) ions leads to derivatives of bicyclononane in the form of N-substituted amides.Adamantane-2-spiro-3'-oxaziridine gives different transformation products, i.e., adamantanone in the first case and 5-azahomoadamantan-4-one in the second.
