84077-22-5Relevant academic research and scientific papers
SYNTHESIS OF MACROCYCLIC TERPENOIDS BY INTRAMOLECULAR CYCLIZATION VII. TOTAL SYNTHESIS OF (+/-)-CUBITENE
Kodama, Mitsuaki,Takahashi, Toshiya,Kojima, Tsutomo,Ito, Sho
, p. 3397 - 3400 (1982)
Stereoselective total synthesis of (+/-)-cubitene, a diterpene isolated from termine soldiers, and its stereoisomer has been achieved utilizing the anion-induced intramolecular cyclization.
SYNTHESIS OF MACROCYCLIC TERPENOIDS BY INTRAMOLECULAR CYCLIZATION XIII. STEREOSELECTIVE SYNTHESIS OF (+/-) CUBITENE, A COMPONENT OF DEFENSE SECRETION OF TERMITES
Kodama, Mitsuaki,Takahashi, Toshiya,Kojima, Tsutomu,Ito, Sho
, p. 7055 - 7062 (2007/10/02)
Stereoselective synthesis of cubitene (1), a novel diterpene isolated from defense secretion of termites, has been accomplished using an intramolecular reaction of α-sulfenyl carbanion with epoxide.Hydride reduction of the ketone 11 obtained by Claisen re
