84097-55-2Relevant articles and documents
FIVE-COORDINATE MANGANESE(II) AND IRON(II) COMPLEXES OF-DIAMINOPYRIDINE
Sangal, S. K.,Sahni, S. K.,Rana, V. B.
, p. 19 - 24 (2007/10/02)
The five-coordinate manganese(II) and iron(II) complexes of two new ligands 2,6-(N,N'-diacetyl) diaminopyridine, (DAP) and 2,6-(N,N'-dibenzoyl) diaminopyridine (DBP) have the formula (MLX2) where M=Mn(II) or Fe(II), L=DAP or DBP; X=Cl(1-), Br(1-), NO3(1-) or NCS(1-).The complexes have been characterised on the basis of elemental analysis, electrical conductance, spectral (infrared and electronic) and magnetic susceptibility data.All the complexes are high-spin and appear to have trigonal bipyramidal stereochemistry.Both DAP and DBP act as N,O,O-tridentate chelating agents.