84109-66-0

Basic information

• Product Name: (2R,4R,5S)-2-phenyl-4-<(1S)-1-hydroxyprop-2-enyl>-5-hydroxy-1,3-dioxane
• CAS NO: 84109-66-0
• Molecular Weight: 236.268
• Mol File: 84109-66-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2R,4R,5S)-2-phenyl-4-<(1S)-1-hydroxyprop-2-enyl>-5-hydroxy-1,3-dioxane(CAS DataBase Reference)
• NIST Chemistry Reference: (2R,4R,5S)-2-phenyl-4-<(1S)-1-hydroxyprop-2-enyl>-5-hydroxy-1,3-dioxane(84109-66-0)
• EPA Substance Registry System: (2R,4R,5S)-2-phenyl-4-<(1S)-1-hydroxyprop-2-enyl>-5-hydroxy-1,3-dioxane(84109-66-0)

Safety Data

• Hazardous Substances Data: 84109-66-0(Hazardous Substances Data)

Upstream product

• 2622-05-1 allylmagnesium bromide 
• 92283-88-0 1,5:2,3-dianhydro-4,6-O-benzylidene-D-allitol 
• 65391-44-8 1,5-anhydro-4,6-O-(R)-benzylidene-D-glucitol 
• 65371-07-5 2,3-di-O-p-tolylsulphonyl-4,6-O-benzylidene-1,5-anhydro-D-glucitol 

Relevant articles and documents

Unusual Stereochemistry in the Copper-catalyses Ring Opening of a Carbohydrate Oxirane with Vinylmagnesium Bromide

The oxirane ring of 4,6-O-benzylidene-1,5:2,3-dianhydro-D-allitol (1) opened regio- and stereo-selectively at C-2 with Me2CuLi and allylmagnesium chloride in the presence of catalytic amounts of CuI.With vinylmagnesium bromide, however, the ring opening of (1) was regioselective but a mixture of stereoisomers (10) and (12) was obtained corresponding to retention and inversion at C-2.A mechanism for the formation of the anomalous retention product (12) is proposed.