84109-67-1Relevant articles and documents
Asymmetric Linear-Selective Hydroformylation of 1,1-Dialkyl Olefins Assisted by a Steric-Auxiliary Strategy
Zhang, Dequan,You, Cai,Li, Xiuxiu,Wen, Jialin,Wen, Jialin,Zhang, Xumu
supporting information, p. 4523 - 4526 (2020/06/04)
Asymmetric hydroformylation of 1,2-dialkyl olefins was reported. In order to increase the enantiomeric induction, steric auxiliary sulfonyl groups were introduced. Using a Rh/Yanphos complex as catalyst, chiral aldehydes were obtained with high enantiosel
Elimination and Addition Reactions. Part 40. The Insignificant Effect of Strain in Higher Order Eliminations in 1,1-bis(phenylsulphonyl) Carbanions with ω-Leaving Groups
Benedetti, Fabio,Stirling, Charles J.M.
, p. 605 - 612 (2007/10/02)
Rates of cyclisation of 1,1-bis(phenylsulphonyl) carbanions bearing distal leaving groups have been determined.The response of the system to solvent effects and to leaving group is similar to that in intramolecular nucleophilic substitution.The system is
STRAIN AND SELECTIVITY: PARTNERS FOR ORGANIC SYNTHESIS
Trost, Barry M.
, p. 139 - 150 (2007/10/02)
The development of two new small-ring conjunctive reagents, (E)-2-(hydrohymethyl)cyclopropyl phenyl sulphide and 1,1-bis(benzenesulphonyl)cyclopropane, are reported.The former permits a synthesis of 2,4-disubstituted cyclobutanones and (E)-4-phenylthio-4-