841277-22-3Relevant academic research and scientific papers
Synthesis of α- and/or γ-benzoyloxy-α,β-enones from α-halo-α,β-enones
Hayashi, Yujiro,Shoji, Mitsuru,Kishida, Satoshi
, p. 681 - 685 (2007/10/03)
Sodium benzoate reacts with α-halo-α,β-enones in the presence of tetrabutylammonium hydrogensulfate or 18-Crown-6 to afford α- and/or γ-benzoyloxylated α,β-enones in good yield. The α/γ and γ/γ′ selectivities are dependent on the substrate and reagent. Sodium benzoate reacts with α-halo-α,β- enones in the presence of tetrabutylammonium hydrogensulfate or 18-Crown-6 to afford α- and/or γ-benzoyloxy-α,β-enones in good yield. The α/γ and γ/γ′ selectivities are dependent on the substrate and reagent.
