84132-35-4Relevant academic research and scientific papers
Phenylthio Migrations in Rearrangements of 2,2-Bisphenylthioethanols
Blatcher, Philip,Warren, Stuart
, p. 1055 - 1066 (2007/10/02)
Thionyl chloride causes rearrangement of the title compounds to give 2,3-bisphenylthiopropenes (12) by a phenylthio shift.The products undergo phenylthio shifts on exposure to light.Some applications to synthesis are described.
Quassinoids. 1. Attempted Intramolecular Diels-Alder Approach for Assembling the ABCD Rings
Voyle, Martyn,Kyler, Keith S.,Arseniyadis, Simeon,Dunlap, Norma K.,Watt, David S.
, p. 470 - 476 (2007/10/02)
A synthetic approach to the quassinoids involved the attempted intramolecular Diels-Alder reaction of the ester 31.The diene component, 4-(phenylthio)-3,5-hexadienoic acid (5) was prepared either by carboxylation of the anion of 3-(phenylthio)-1,3-pentadi
