84174-36-7Relevant articles and documents
Rhodium-catalysed substitutive arylation of cis-allylic diols with arylboroxines
Miura, Tomoya,Takahashi, Yusuke,Murakami, Masahiro
, p. 595 - 597 (2007)
Substitutive arylation of cis-allylic diols occurs upon treatment with arylboroxines in the presence of a rhodium(i) catalyst; the reaction proceeds through the addition of an intermediate arylrhodium(i) species across the carbon-carbon double bond and su
The Palladium-Catalyzed Cross-Coupling Reaction of Organosilicon Compounds with Allylic Carbonates or Diene Monoxides
Matsuhashi, Hayao,Asai, Satoshi,Hirabayashi, Kazunori,Hatanaka, Yasuo,Mori, Atsunori,Hiyama, Tamejiro
, p. 1943 - 1952 (2007/10/03)
The cross-coupling reaction of allylic carbonates with organosilanes was found to proceed without fluoride ion activation under mild conditions by using a coordinatively unsaturated palladium complex as a catalyst.The reaction was assumed to proceed through an allylpalladium alkoxide derived from the allylic carbonate substrate and a palladium(0) species, the alkoxo ligand activating the organosilicon reagent.Likewise, diene monoxides also underwent cross-coupling with alkenyl- and arylfluorosilanes in moderate to high yields.