842136-40-7Relevant academic research and scientific papers
Highly efficient stereoselective catalytic C(sp3)-H insertions with donor rhodium carbenoids generated from cyclopropenes
Archambeau, Alexis,Miege, Frederic,Meyer, Christophe,Cossy, Janine
supporting information, p. 11540 - 11544 (2013/01/15)
Rings of five and six: Donor alkenyl rhodium carbenoids generated from 3,3-dimethylcyclopropenylcarbinols exhibit high reactivity in intramolecular C-H insertions. The reactions proceed under remarkably mild conditions, tolerate the presence of the free hydroxy group, and afford an efficient and stereoselective access to a variety of functionalized carbocycles and oxygen heterocycles. Copyright
