84269-40-9Relevant academic research and scientific papers
Photosensitized Oxidation of Furans. Part 7. Solvent Effects in Thermal Conversion of the endo-Peroxides of Arylfurans
Graziano, M. Liliana,Iesce, M. Rosaria,Chiosi, Sergio,Scarpati, Rachele
, p. 2071 - 2074 (2007/10/02)
Thermal conversion of the endo-peroxides of the arylfurans (1) in a polar aprotic solvent leads to aroylenol esters (4) and diaroyl epoxides (3), the predominance of one over being concentration dependent.The results can be rationalized on the basis of th
PHOTOSENSITIZED Oxidation of Furans. Part 4. Influence of the Substituents on the Behaviour of the endo-Peroxides of Furans
Graziano, M. Liliana,Iesce, M. Rosaria,Scarpati, Rachele
, p. 2007 - 2012 (2007/10/02)
A comparison of the ehaviour of endo-peroxides of the β-furoic esters (1a, b and d-f) and of the furans (1c or g), with the same 2,5-substituents, shows that the thermal instability of these compounds is related to the electron density in the bicyclic unsaturated ring.This also accounts for the higher stability of the alkyl-substituted endo-peroxides (1a-c) as compared with that of the aryl-substituted derivatives (1d-g), as well as for the different course of the thermal conversion in the two series.
