84303-24-2Relevant academic research and scientific papers
Synthesis of 11- and 15-Oxygenated Steroids. The Course of 8,14-Dienes Oxidation by Chromic Acid
Anastasia, Mario,Allevi, Pietro,Fiecchi, Alberto,Galli, Giovanni,Gariboldi, Pierluigi,Scala, Antonio
, p. 686 - 689 (2007/10/02)
3β-Acetoxy-9α-hydroxy-5α-cholest-8(14)-en-15-one, 3β-acetoxy-8α,9α-epoxy-14α-hydroxy-5α-cholestan-15-one, and 3β-acetoxy-8α,9α-epoxy-14α-hydroxy-5α-cholestane-11,15-dione were obtained by oxidizing 3β-acetoxy-5α-cholesta-8,14-diene with various amounts of Jones reagent or performing the reaction under different temperature conditions.The epoxy ketones were also obtained by independent synthesis.
