84308-08-7Relevant academic research and scientific papers
CHEMOSELECTIVE AND STEREOSELECTIVE ADDITION OF ORGANOCUPRATES TO α-OXOKETENE DITHIOACETALS
Dieter, R. Karl,Fishpaugh, Jeffrey R.,Silks, Louis A.
, p. 3751 - 3754 (2007/10/02)
The chemoselective and stereoselective addition of organocuprates to cyclic α-oxoketene dithioacetals affords predominately the E vinylogous thioesters.An acylic α-oxoketene dithioacetal affords the Z vinylogous thioester stereoselectively.The observed selectivities are dependent upon substrate structure and the organocopper reagent.
