84355-65-7Relevant academic research and scientific papers
Cycloadditions of Cyanoketenes to Cinnamylideneamines and Benzylideneamines. Synthetic Scope, Stereochemistry, and Mechanism
Moore, Harold W.,Hughes, Gregory,Srinivasachar, Kasturi,Fernanadez, Mario,Nguyen, Nghi V.,et al.
, p. 4231 - 4238 (2007/10/02)
A study of the cycloadditions of cyanoketenes to cynnamylideneamines and benzylideneamines is presented.The size and degree of unsaturation of the imine substituents were
CYANOKETENES. CYCLOADDITIONS OF CHLOROCYANOKETENE TO α,β-UNSATURATED IMINES
Moore, Harold W.,Hughes, Gregory
, p. 4003 - 4006 (2007/10/02)
Chlorocyanoketene cycloadds to cinnamylideneamines to give β-lactams, δ-lactams and pyridones.The periselectivity and stereoselectivity of these cycloadditions is markedly influenced by the N-substituent as well as the β- substituents of the imines.
