84363-47-3Relevant academic research and scientific papers
The efficient allylations of 2-oxocarboxylic acids. Synthesis of 2-allyl derivatives of 2-hydroxycarboxylic acids
Kumar, Subodh,Kaur, Pervinder,Chimni, Swapandeep Singh
, p. 573 - 574 (2002)
2-Oxocarboxylic acids or their sodium salts undergo indium-mediated allylation with allyl bromide cinnamyl bromide and ethyl 4- bromocrotonate to provide the corresponding 2-allyl derivatives of glycolic lactic mandelic and malic acids. In the case of rea
Synthesis of γ, δ-unsaturated glycolic acids via sequenced brook and Ireland - Claisen rearrangements
Schmitt, Daniel C.,Johnson, Jeffrey S.
supporting information; experimental part, p. 944 - 947 (2010/06/16)
(Figure Presented) Organozinc, -magnesium, and -lithium nucleophiles Initiate a Brook/lreland-Clalsen rearrangement sequence of allylic silyl glyoxylates resulting in the formation of γ, δ-unsaturated a-silyloxy acids.
