84363-65-5Relevant academic research and scientific papers
Direct transformation of terminal alkynes to branched allylic sulfones
Xu, Kun,Khakyzadeh, Vahid,Bury, Timm,Breit, Bernhard
supporting information, p. 16124 - 16127 (2015/01/09)
A new strategy for the transformation of terminal alkynes to branched allylic sulfones was developed. Using a Rh(I)/DPEphos/benzoic acid catalyst system, terminal alkynes react with sulfonyl hydrazides to produce branched allylic sulfones with good to exc
Facile synthesis of vinyl sulfones from β-bromo alcohols
Lee, Jae Wook,Lee, Chi-Wan,Jung, Jin Hang,Oh, Dong Young
, p. 2897 - 2902 (2007/10/03)
Vinyl sulfones are synthesized in good yields by dehydration of β- hydroxy sulfones derived from β-bromo alcohols.
1-BENZENESULFONYL-2-TRIMETHYLSILYLETHANE AND 1-BENZENESULFONYL-1-CHLORO-2-TRIMETHYLSILYLETHANE; EFFICIENT REAGENTS FOR SULFONYL-α-VINYLATION
Hsiao, C-N.,Shechter, H.
, p. 3455 - 3458 (2007/10/02)
1-Benzenesulfonyl-2-trimethylsilylethane and 1-benzenesulfonyl-1-chloro-2-trimethylsilylethane are convertable to 1-benzenesulfonyl-1-chloro-1-substituted-2-trimethylsilylethanes which undergo elimination by fluoride ion to give phenyl α-substituted-vinyl
