84369-73-3Relevant academic research and scientific papers
Absorption Kinetics of Photochemical Reactions of 2,4,6-Triisopropylbenzophenone and Its Derivatives in Benzene at Room Temperature Studied by Nanosecond Spectroscopy. 2. Laser Chemistry, Molecular Dynamics, collisions, and Energy Transfer
Nakayama, Toshihiro,Kuramoto, Tetsunobu,Hamanoue, Kumao,Teranishi, Hiroshi
, p. 5689 - 5695 (2007/10/02)
Nanosecond laser photolyses of 2,4,6-triisopropylbenzophenoses (TIB-X) have been performed in benzene at room temperature, and the characteristic absorption bands due to the highly hindered triplet states are observed around 600 about 800 nm.For the meta-
Novel Photoreversible Cyclization of Acyl-Substituted 2,4,6-Triisopropylbenzophenones
Ito, Yoshikatsu,Giri, Brij Pal,Nakasuji, Masaaki,Hagiwara, Toshiya,Matsuura, Teruo
, p. 1117 - 1122 (2007/10/02)
A photoreversible cyclization of 3'(or 4')-X-2,4,6-triisopropylbenzophenones 1 (X=C6H5CO, 2,4,6-(i-Pr)3C6H2CO, CH3CO) into the corresponding 2 was investigated in benzene at 313 nm.When the meta (2,4,6-(i-Pr)3C6H2CO) derivative 1d was photolized, an addit
Photocyclization Reaction and Triplet Lifetime of Hindered o-Alkyl Benzophenones
Ito, Yoshikatsu,Umehara, Yasutoshi,Yamada, Yutaka,Matsuura, Teruo
, p. 1160 - 1161 (2007/10/02)
The triplet lifetimes of hindered 4'-substituted-2,4,6-tri-isopropylbenzophenones decrease (increase) with the increasing electron-donating (withdrawing) ability of the ring substituents; this is the opposite effect to that expected from the rate of the i
