84392-23-4

Basic information

• Product Name: 2-[4-(TRIFLUOROMETHYL)PHENYL]BENZALDEHYDE
• Synonyms: 4'-(TRIFLUOROMETHYL)-2-BIPHENYLCARBOXALDEHYDE;4'-(TRIFLUOROMETHYL)[1,1'-BIPHENYL]-2-CARBALDEHYDE;4'-(TRIFLUOROMETHYL)[1,1'-BIPHENYL]-2-CARBOXALDEHYDE;4'-TRIFLUOROMETHYL-BIPHENYL-2-CARBALDEHYDE;AKOS BAR-0246;2-[4-(TRIFLUOROMETHYL)PHENYL]BENZALDEHYDE
• CAS NO: 84392-23-4
• Molecular Formula: C₁₄H₉F₃O
• Molecular Weight: 250.22
• Mol File: 84392-23-4.mol
• Article Data: 17

Chemical Properties

• Boiling Point: 324.6 °C at 760 mmHg
• Flash Point: >121℃
• Appearance: /
• Density: 1.273 g/mL at 25 °C
• Refractive Index: n20/D1.552
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C
• CAS DataBase Reference: 2-[4-(TRIFLUOROMETHYL)PHENYL]BENZALDEHYDE(CAS DataBase Reference)
• NIST Chemistry Reference: 2-[4-(TRIFLUOROMETHYL)PHENYL]BENZALDEHYDE(84392-23-4)
• EPA Substance Registry System: 2-[4-(TRIFLUOROMETHYL)PHENYL]BENZALDEHYDE(84392-23-4)

Safety Data

• Hazard Codes: Xi,N,Xn
• Statements: 36/37/38-51/53-22
• Safety Statements: 26-36/37/39-61
• RIDADR: UN 3082 9 / PGIII
• WGK Germany: 3
• Hazardous Substances Data: 84392-23-4(Hazardous Substances Data)

Usage

Uses

2-[4-(Trifluoromethyl)Phenyl]Benzaldehyde is a useful reactant for organic reactions.

Upstream product

• 255837-15-1 2-bromo-4’-trifluoromethyl-1,1’-biphenyl 
• 68-12-2 N,N-dimethyl-formamide 
• 128796-39-4 4-trifluoromethylphenylboronic acid 
• 89-98-5 2-chloro-benzaldehyde 
• 6630-33-7 ortho-bromobenzaldehyde 
• 109541-76-6 tris(4-(trifluoromethyl)phenyl)bismuthane 
• 40138-16-7 2-formylbenzene boronic acid 
• 98-56-6 4-chlorobenzotrifluoride 
• 583-55-1 1-Bromo-2-iodobenzene 
• 455-13-0 4-Iodobenzotrifluoride 

Downstream Products

• 84392-17-6 4'-(trifluoromethyl)-2-biphenylcarboxylic acid 
• 1292302-57-8 C₂₁H₁₆F₃NO₂S 
• 1304461-17-3 C₂₁H₁₆F₃NO₂S 

Relevant articles and documents

Electrochemical Decarboxylative Cyclization of α-Amino-Oxy Acids to Access Phenanthridine Derivatives

Phenanthridines are a class of useful heterocycles in the field of drug development. In this work, a method via electrochemical decarboxylative cyclization of α-amino-oxy acids to access phenanthridine derivatives was developed. This reaction proceeded th

Biphenyl Cyclobutenone Photoelectrocyclizations

In this work, we demonstrate that readily available conjugated bis-aryl cyclobutenones undergo photoelectrocyclization reactions to give the corresponding dihydrophenanthrene cyclobutanones when exposed to 350 nm light, TFA, and TMSCl. We have also found that cyclobutenone electrocyclizations and cycloreversions are in equilibrium.

Insights into the Catalytic Activity of [Pd(NHC)(cin)Cl] (NHC=IPr, IPrCl, IPrBr) Complexes in the Suzuki–Miyaura Reaction

The influence of C4,5-halogenation on palladium N-heterocyclic carbene complexes and their activity in the Suzuki–Miyaura reaction were investigated. Two [Pd(NHC)(cin)Cl] complexes bearing IPrCl and IPrBr ligands (IPr=1,3-bis(2,6-diisopropyl-phenyl)imidazol-2-ylidene; cin=cinnamyl) were synthesized. After determining the electronic and steric properties of these ligands, their properties were compared to those of [Pd(IPr) (cin)Cl]. The three palladium complexes were studied by using DFT calculations to delineate their behavior in the activation step leading to the putative 12-electron active catalyst. Experimentally, their catalytic activity in the Suzuki–Miyaura reaction involving a wide range of coupling partners (30 entries) at low catalyst loading was studied.