844638-86-4

Basic information

• Product Name: Carbamic acid, [(2-nitrophenyl)sulfonyl](1-propyl-3-butenyl)-, 1,1-dimethylethyl ester
• CAS NO: 844638-86-4
• Molecular Formula: C18H26N2O6S
• Molecular Weight: 398.48
• Mol File: 844638-86-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Carbamic acid, [(2-nitrophenyl)sulfonyl](1-propyl-3-butenyl)-, 1,1-dimethylethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Carbamic acid, [(2-nitrophenyl)sulfonyl](1-propyl-3-butenyl)-, 1,1-dimethylethyl ester(844638-86-4)
• EPA Substance Registry System: Carbamic acid, [(2-nitrophenyl)sulfonyl](1-propyl-3-butenyl)-, 1,1-dimethylethyl ester(844638-86-4)

Safety Data

• Hazardous Substances Data: 844638-86-4(Hazardous Substances Data)

Upstream product

• 3521-91-3 hept-1-en-4-ol 
• 198572-71-3 N-(tert-butoxycarbonyl)-2-nitrobenzenesulfonamide 

Downstream Products

• 844638-88-6 N-cyclohex-2-enyl-2-nitro-N-(1-propyl-but-3-enyl)-benzenesulfonamide 
• 61475-92-1 (rac)-(2R,4aS,5R,8aS)-1-benzyl-5-methyl-2-propyl-decahydroquinoline 
• 27766-71-8 (rac)-(2R,4aS,5R,8aS)-5-methyl-2-propyl-decahydroquinoline 

Relevant articles and documents

Diastereoselective synthesis of 2,5-disubstituted decahydroquinolines via ring-rearrangement metathesis and zirconium-mediated cyclization

A diastereoselective approach to 2,5-substituted decahydroquinolines by zirconium-mediated cyclization of unsaturated α,α′- disubstituted piperidines II is described. The required piperidines could be obtained from secondary sulfonamides III via ruthenium-catalyzed ring-rearrangement metathesis (RRM) in high yields. Racemic trans-195A and 2-epi-trans-195A were synthesized in 8 steps starting with butyraldehyde and cyclohex-2-enol.