844643-38-5

Upstream product

• 917-95-3 t-butylnitrite 
• 54120-42-2 N-(3-bromophenyl)-1,1,1-trimethyl-N-(trimethylsilyl)silanamine 

Downstream Products

• 844643-76-1 bis-{1-[3-(N-tert-butyl-N-hydroxyamino)phenylimino]ethyl}pyridine 
• 844643-79-4 N-[3-(N-tert-butyl-N-hydroxyaminophenyl)]-(2-pyridyl)ethanimine 
• 844643-70-5 N-[3-(N-tert-butyl-N-hydroxyaminophenyl)]-(2-pyridyl)methanimine 
• 844643-50-1 3-(N-tert-butyl-N-hydroxyamino)aniline 

Relevant academic research and scientific papers

Imino- and bis-imino-pyridines with N-ter-butyl-N-aminoxyl group: Synthesis, oxidation and use as ligand towards M2+ (Mn, Ni, Zn) and Gd3+

Imino- and bis-iminopyridine ligands bearing N-ter-butylhydroxy groups were synthesized by the condensation reaction between a N-ter-butylhydroxy substituted aniline and 2-formylpyridine, 2-acetylpyridine and 2,6-bis-acetylpyridine. The N-ter-butylaminoxy radicals obtained after oxidation using PbO2 or Ag2O were studied by EPR spectroscopy in solution. Indeed, complete decomposition was observed during isolation of these radical derivatives. The N-ter-butylhydroxy substituted ligands obtained were complexed with Mn2+, Ni2+, Zn2+ and Gd 3+ salts; the obtained complexes were characterized and oxidized to give the aminoxy analogs, which were studied using IR, UV and EPR spectroscopies.