84500-07-2Relevant academic research and scientific papers
Hydridoiridium(III) Complexes with Terminal and Bridging Thio- and Selenocyanate
Olgemoeller, Bernhard,Beck, Wolfgang
, p. 2360 - 2364 (2007/10/02)
The thio- and selenocyanato complexes (Ph3P)2(CO)(Cl)(H)IrX 1 (X = SCN) and 2 (X = SeCN) have been prepared from the corresponding tetrafluoroborato- and trifluoromethanesulfonato-compounds (X = BF4, CF3SO3).The SCN ligand in 1 is S-bonded. 2 was obtained as a mixture of linkage isomers.The reaction of 2 with the tetrafluoroborato-complex (Ph3P)2(CO)(Cl)(H)IrFBF3 gives the salt +BF4- which contains the selenocyanate-bridged cation as a mixture of stereoisomers.
