845508-87-4Relevant academic research and scientific papers
Stereoselective and diversity-oriented synthesis of trisubstituted allylic alcohols and amines
Schmidt, Yvonne,Breit, Bernhard
supporting information; experimental part, p. 11789 - 11796 (2011/11/06)
Stereoselective and diversity-oriented synthesis of trisubstituted olefins was achieved by using ortho-diphenylphosphanyl benzoate (o-DPPB) as a directing group for allylic substitution. The starting point of this methodology was a set of α-methylene alde
Equilibrium control in enyne metathesis: Crossover studies and the kinetic reactivity of (E,Z)-1,3-disubstituted-1,3-dienes
Giessert, Anthony J.,Diver, Steven T.
, p. 1046 - 1049 (2007/10/03)
(Chemical Equation Presented) The stereoselectivity of diene bond formation in the ruthenium-carbene mediated intermolecular enyne metathesis was studied. Initial reaction between an alkyne and 1-hexene gave mixtures of E- and Z-isomers in the newly forme
