84551-62-2Relevant academic research and scientific papers
14-Methyl Steroids. Part 2. Total Synthesis of (+/-)-14α-Methyl-19-norsteroids
Bull, James R.,Bischofberger, Karl
, p. 2723 - 2727 (2007/10/02)
trans-1,6-Dimethylbicyclononane-2,7-dione (1) is converted, via regiospecific homologation at C-2, into trans-1,6-dimethyl-2-methylenebicyclononane-3,7-dione (6).Conjugate alkylation of (6) with m-methoxybenzylmagnesium chloride followed by
Total Synthesis of (+/-)-14α-Methyl-19-norsteroids
Bischofberger, Karl,Bull, James R.
, p. 1051 - 1052 (2007/10/02)
Trans-1,6-Dimethylbicyclononane-2,7-dione was converted, in six steps, into a mixture of (+/-)-3-methoxy-14-methyl-14α-estra-1,3,5(10),9(11)-tetraen-17-one and the corresponding Δ8-isomer.
