845512-99-4

Upstream product

• 845512-97-2 8-(tert-butyl-dimethyl-silanyloxy)-9-(tert-butyl-dimethyl-silanyloxymethyl)-3,4a,8-trimethyl-2-pent-3-enyl-2,3,4,4a,5a,8,9,10a,11,11a-decahydro-1,5,10-trioxa-cyclohepta[b]naphthalen-3-ol 
• 845512-95-0 [7-[3-(tert-butyl-diphenyl-silanyloxy)-propyl]-4a,10a-dimethyl-3-(triethyl-silanyloxy)-5-(triisopropyl-silanyloxy)-decahydro-1,8,10-trioxa-anthracen-2-yl]-acetic acid 

Downstream Products

• 845513-01-1 C₈₀H₁₃₈O₁₂Si₅ 
• 884005-43-0 C₈₄H₁₄₆O₁₂Si₅ 
• 884005-41-8 C₇₁H₁₁₆O₁₄Si₃ 

Relevant academic research and scientific papers

Total synthesis of gambierol: Subunit coupling and completion

The preceding manuscript detailed our synthesis of the gambierol A-C and F-H ring precursors. Reported herein is a description of the coupling of the two precursors and the conversion of the coupled material into gambierol. Coupling of the subunits involv

The total synthesis of gambierol

This communication describes the total synthesis of the marine polyether toxin, gambierol. This work couples our iterative C-glycoside/enol ether-olefin metathesis strategy to the subunits with a unique olefin metathesis/carbonyl olefination reaction to bring the subunits together. Copyright