845536-63-2

Upstream product

• 79271-56-0 triethylsilyl trifluoromethyl sulfonate 
• 845536-61-0 2'-[benzyl-(2,4,6-trimethylbenzenesulfonyl)amino]-1'-phenylpropyl (2S,3R,1'S,2'R,2''S,3''S,5''S)-3-[2-(6''-benzyloxy-2''-methoxymethoxy-3'',5''-dimethylhexyl)-3,5,6-trimethoxy-4-methylphenyl]-2-methyl-3-triethylsilanyloxy-propionate 
• 845536-46-1 (2S,3R,2'S,3'S,5'S)-3-[2-(6'-benzyloxy-2'-methoxymethoxy-3',5'-dimethylhexyl)-3,5,6-trimethoxy-4-methylphenyl]-2-methyl-3-triethylsilanyloxypropan-1-ol 
• 845536-62-1 (2S,3R,2'S,3'S,5'S)-3-[2-(6'-benzyloxy-2'-methoxymethoxy-3',5'-dimethylhexyl)-3,5,6-trimethoxy-4-methylphenyl]-2-methyl-3-triethylsilanyloxypropanal 
• 845536-49-4 (1R,2R,3S,4S,2'S,3'S,5'S)-1-[2-(6'-benzyloxy-2'-methoxymethoxy-3',5'-dimethylhexyl)-3,5,6-trimethoxy-4-methylphenyl]-2,4-dimethyl-1-triethylsilanyloxyhex-5-en-3-ol 
• 76513-69-4 (2-trimethylethylsilylethoxy)methyl chloride 

Downstream Products

• 845536-58-5 (1R,2R,3S,4S,2'S,3'S,5'S)-1-[2-(6'-benzyloxy-2'-methoxymethoxy-3',5'-dimethylhexyl)-3,5,6-trimethoxy-4-methylphenyl]-2,4-dimethyl-3-(2-trimethylsilanylethoxymethoxy)hex-5-en-1-ol 

Relevant academic research and scientific papers

Application of the Doetz reaction to construction of a major portion of the ansa macrocycle (-)-kendomycin

(Chemical Equation Presented) A Doetz reaction employing a terminal alkyne and a Fischer-type alkenylchromium carbenoid led to a pentasubstituted benzene from which a major portion of the Streptomyces metabolite (-)-kendomycin was synthesized.