84568-16-1

Upstream product

• 78823-83-3 (2,4-pentadienyl)trimethylstannane 
• 84568-08-1 5-Bromo-2-methoxy-3-methyl-1,4-benzoquinone 
• 105103-88-6 3-bromo-4,6-dimethoxy-5-methyl-2-(2,4-pentadienyl)phenol 
• 84568-10-5 2-bromo-5-methoxy-6-methyl-3-(2,4-pentadienyl)-1,4-benzoquinone 
• 109034-88-0 2-azido-5-methoxy-6-methyl-3-(2,4-pentadienyl)-1,4-benzoquinone 

Relevant academic research and scientific papers

Copper-Catalyzed Double Cyclization Reaction of Azidoquinones: One-Step Synthesis of Dihydropyrroloquinones and Related Quinolinoquinones

Intramolecular cyclization of 2-azido-3-(2,4-pentadienyl)-1,4-quinone (7) has been examined in the presence of metal catalysts MLn (L=acetylacetonato).Copper or Cu(acac)2 catalysts exhibited the highest catalytic activity both to the decomposition of the

SYNTHETIC APPROACH TOWARD MITOMYCINS. EFFICIENT SYNTHESIS OF MITOSANE PRECURSORS FROM (2,4-PENTADIENYL)-p-QUINONES

Introduction of 2,4-pentadienyl side chain to halogenated p-quinones is performed with (2,4-pentadienyl)trimethylstannane to afford 2-halo-3-(2,4-pentadienyl)-1,4-quinones.Pyrolytic decomposition of the corresponding azidoquinones derived from the obtaine