845827-30-7Relevant academic research and scientific papers
Silver(I)-Catalyzed deprotection of p -methoxybenzyl ethers: A mild and chemoselective method
Kern, Nicolas,Dombray, Thomas,Blanc, Aurelien,Weibel, Jean-Marc,Pale, Patrick
, p. 9227 - 9235,9 (2012/12/12)
The p-methoxybenzyl protecting group (PMB) on various alcohols and an acid was efficiently and selectively cleaved by the action of a catalytic amount of silver(I) hexafluoroantimonate combined with 0.5 equiv of 1,3,5- trimethoxybenzene in dichloromethane at 40 °C.
Synthesis and self-assembly of functionalized donor-σ-acceptor molecules
Li, Hengfeng,Homan, Edwin A.,Lampkins, Andrew J.,Ghiviriga, Ion,Castellano, Ronald K.
, p. 443 - 446 (2007/10/03)
(Chemical Equation Presented) 3,5,7-Tris(arylmethyl)-1-aza-adamantanetrione donor-σ-acceptor compounds have been synthesized in four steps. Computational and 1H NMR analyses rationalize the solubility, gelation, and conformational properties of the C3-symmetric molecules toward employing σ-coupled donor-acceptor interactions in molecular self-assembly.
