84602-26-6Relevant academic research and scientific papers
Solvent-Free Henry and Michael Reactions with Nitroalkanes Promoted by Potassium Carbonate as a Versatile Heterogeneous Catalyst
Bosica, Giovanna,Polidano, Kurt
, (2017)
The use of a simple weak inorganic base such as potassium carbonate facilitated the formation of carbon-carbon bonds through both the Henry and the Michael reactions with nitrocompounds. The application of this catalyst under environmentally friendly solventless heterogeneous conditions gave satisfactory to good yields of β-nitroalcohols, involving aliphatic and aromatic starting materials, as well as high to excellent yields in the formation of Michael adducts using several different Michael acceptors and nitroalkanes.
Conjugate Addition of Nitroalkanes to an Acrylate Equivalent. Stereocontrol at C-α of the Nitro Group through Double Catalytic Activation
Garcia, Jesus M.,Maestro, Miguel A.,Oiarbide, Mikel,Odriozola, Jose M.,Razkin, Jesus,Palomo, Claudio
supporting information; experimental part, p. 3826 - 3829 (2009/12/06)
Figur Presented An unprecedented highly selective direct conjugate addition of prochiral nitroalkanes (R ≠ H) to acrylate equivalents is described. The method employs a unique Lewis acid/Bronsted base/MS ternary catalytic system and affords products with
