84602-91-5Relevant academic research and scientific papers
Phase Transfer Catalyzed (PTC) Reactions of Allylic Sulphones with Electrophilic Alkenes
Jonczyk, A.,Radwan-Pytlewski, T.
, p. 1161 - 1167 (2007/10/02)
Allylic sulphones 1a-d reacted with electrophilic alkenes 2a-e in the presence of concentrated aq.NaOH solution and tetra-n-butylammonium bromide (TBAB), as a catalyst (phase transfer catalysis, PTC), to give either monosubstituted products 3 and/or 4 or
Application of the Catalytic Two-Phase System to Carbanionic Reactions of Allyl Sulfones
Jonczyk, Andrzej,Radwan-Pytlewski, Tadeusz
, p. 910 - 912 (2007/10/02)
Allyl sulfones are easily converted into carbanions in the presence of concentrated aqueous NaOH solution and a quaternary ammonium catalyst.These carbanions readily react with alkyl halides, electrophilic alkenes, or perchloroalkanes.
