84602-95-9

Upstream product

• 86777-85-7 phenylprenylsulfone anion (ref:11) 
• 873-55-2 sodium benzenesulfonate 
• 15874-80-3 3-methyl-1-(phenylsulfonyl)but-2-ene 

Downstream Products

• 88958-81-0 4-Benzenesulfonyl-4-chloro-6-methyl-hept-5-enoic acid 
• 88958-93-4 1-(1-Benzenesulfonyl-3-methyl-but-2-enyl)-4-nitro-naphthalene 
• 56631-62-0 4-Methyl-2-(phenylsulfonyl)-1-phenyl-1,3-pentadiene 
• 88958-77-4 C₁₈H₁₉ClO₂S 
• 88958-86-5 2-Benzenesulfonyl-3-(4-methoxy-phenyl)-2-(2-methyl-propenyl)-oxirane 
• 88958-84-3 2-Benzenesulfonyl-2-(2-methyl-propenyl)-3-naphthalen-2-yl-oxirane 
• 88958-79-6 4-Benzenesulfonyl-4-chloro-6-methyl-hept-5-enenitrile 
• 15874-80-3 3-methyl-1-(phenylsulfonyl)but-2-ene 
• 93297-03-1 1,6-Bis benzenesulfonyl-3,3,4,4-tetramethyl-hexa-1,5-diene E,E 
• 133301-14-1 1,4-Bis benzenesulfonyl-3,3,6-trimethyl-hepta-1,5-diene E 
• 88958-85-4 1-Benzenesulfonyl-1-(4-methoxy-phenyl)-4-methyl-pent-3-en-2-one 
• 88958-82-1 2-Benzenesulfonyl-2-(2-methyl-propenyl)-3-phenyl-oxirane 
• 88958-80-9 C₁₉H₂₁ClO₄S₂ 
• 88958-75-2 (3-Chloro-5-methyl-hex-4-ene-3-sulfonyl)-benzene 

Relevant academic research and scientific papers

Phase-Transfer Catalytic (PTC) Chlorination of Allylic Sulphones

Phase-transfer catalytic reactions of allylic sulphones with hexachloroethane or carbon tetrachloride afford mono- or dichlorinated products, with high yields. - Key words: phase transfer catalysis (PTC); allylic sulphones; halogenophilic reaction

Application of the Catalytic Two-Phase System to Carbanionic Reactions of Allyl Sulfones

Allyl sulfones are easily converted into carbanions in the presence of concentrated aqueous NaOH solution and a quaternary ammonium catalyst.These carbanions readily react with alkyl halides, electrophilic alkenes, or perchloroalkanes.

SOME CARBANIONIC REACTIONS OF α-CHLOROALLYL SULFONES

The chlorination of 3-methyl-2-butenyl phenyl sulfone with either hexachloroethane or 1,1-dichloro-3-methyl-2-butenyl phenyl sulfone in basic medium gives rise to 1-chloro-3-methyl-2-butenyl phenyl sulfone which in turn reacts in situ with electrophilic c

α-bENZENESULFONYL FREE RADICALS

Allylic α-halosulfones give, on reduction with tri n-butyl tin hydride, sizeable amounts of dimers.It so appears that free radicals can indeed be formed α to an arenesulfonyl group and coupling can occur during tin hydride reduction of halides