84615-33-8Relevant articles and documents
Spectra, Ionization Constants, and Rates of Oxidation of 1,4-Dimercaptobenzene and Properties of the p-Mercaptophenylthiyl and p-Benzodithiyl Anion Radicals
Armstrong, D. A.,Sun, Qun,Tripathi, G. N. R.,Schuler, R. H.,McKinnon, D.
, p. 5611 - 5617 (2007/10/02)
In basic solution, p-dimercaptobenzene, which is found to have pKa's of 6.0 and 7.7, is rapidly oxidized by azide radical (k = 7.4*109 M-1 s-1) to p-benzodithiyl radical anion, the sulfur analog of p-benzosemiqu