84642-45-5

Basic information

• Product Name: Benzoic acid 2-trimethylsilanylmethyl-allyl ester
• Synonyms: Benzoic acid 2-trimethylsilanylmethyl-allyl ester
• CAS NO: 84642-45-5
• Molecular Weight: 248.397
• Mol File: 84642-45-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzoic acid 2-trimethylsilanylmethyl-allyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Benzoic acid 2-trimethylsilanylmethyl-allyl ester(84642-45-5)
• EPA Substance Registry System: Benzoic acid 2-trimethylsilanylmethyl-allyl ester(84642-45-5)

Safety Data

• Hazardous Substances Data: 84642-45-5(Hazardous Substances Data)

Upstream product

• 13170-43-9 (trimethylsilyl)methylmagnesium chloride 

Downstream Products

• 72048-00-1 methyl 1-(methoxycarbonyl)-2-phenyl-4-methylenecyclopentane-1-carboxylate 

Relevant articles and documents

Preparation of 2-(trimethylsilyl)methyl-2-propen-1-ol derivatives by cobalt catalyzed sp2-sp3 coupling

A practical, operationally simple preparation of 2-(trimethylsilyl)methyl-2-propen-1-ol derivatives is described. The cobalt catalyzed coupling of a protected vinyl halide with trimethylsilylmethylmagnesium chloride shows excellent functional group tolerance and provides these synthetically useful allyl silanes in good overall yield. By this method, the use of highly concentrated organolithium reagents, complex reaction protocols, and expensive starting materials is avoided.