84645-40-9Relevant academic research and scientific papers
NEW METHODS AND REAGENTS IN ORGANIC SYNTHESIS. 32. LITHIUM TRIMETHYLSILYLDIAZOMETHANE: A NEW SYNTHON FOR THE PREPARATION OF 1,2,3-TRIAZOLES
Aoyama, Toyohiko,Sudo, Kimio,Shioiri, Takayuki
, p. 3849 - 3851 (2007/10/02)
Lithium trimethylsilyldiazomethane, prepared from trimethylsilyldiazomethane and n-butyl lithium, reacts smoothly with various nitriles to give 4-substituted 5-trimethylsilyl-1,2,3-triazoles in excellent yields.KEYWORDS-trimethylsilyldiazomethane; lithiat
